Product ID:MANGANESE AA STANDARD
MSDS Date:10/13/1995
FSC:6810
NIIN:00D004415
MSDS Number: BYTDT

SPECTRUM CHEMICAL MFG CORP.

14422 SOUTH SAN PEDRO STREET
GARDENA, CA 90248-2027
US

Emergency Phone: 310-516-8000 800-424-9300(CHEMTREC)

Info Phone: 310-516-8000

Preparer: E. BRULL

Cage: 63415

SPECTRUM LABORATORY PRODUCTS INC

GARDENA, CA 90248-2027 US

Telephone: 310-516-9843

Cage: 63415

MANGANESE (SARA 313)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 0.1-3.1%

OSHA PEL C 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9495

NITRIC ACID (SARA 302/313) (CERCLA)

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2 - 5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM/4 STEL; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 97.9%

LD50 LC50 Mixture:LC50 INHAL RAT 67PPM/4HRS (NITRIC ACID)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:**CORROSIVE** EYES:MAY CAUSE SEVERE
IRRITATION OR BURNS.SKIN:MAY CAUSE IRRITATION OR BURNS.INGEST:MAY
BE FATAL OR CAUSE GI TRACT IRRITATION.INHAL:MAY CAUSE RESPIRATORY
IRRITATION.CHRONIC:REPEATED EXPO SURES TO THIS MATERIAL MAY
PREDISPOSE PERSON TO BRONCHIAL INFECTIONS.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:INHAL:COUGHING,CHOKING,SHORTNESS OF
BREATH.SKIN:ITCHING,SCALING,REDDENING,BLISTERING.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH COLD WATER.CALL
DOCTOR IF NEEDED.EYES:REMOVE CONTACT LENSES.FLUSH WITH WATER FOR 15
MINUTES.CALL DOCTOR.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR
ARTIFICIAL RESPIRATION IF NEEDED.CALL DOCTOR.INGEST:DO NOT INDUCE
VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE
WATER OR MILK.LOOSEN CLOTHING.

Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE.USE MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:**OXIDIZER** THIS ITEM MAY SUPPLY OXYGEN
TO SUPPORT A FIRE.

Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE
EQUIPMENT.VENTILATE AREA.DILUTE WITH WATER AND MOP UP.SOAK UP WITH
A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER
CONTAINER FOR DISPOSAL.
Neutralizing Agent:NOT REPORTED.

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM
HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS.
Other Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID
SKIN AND EYE CONTACT.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NIOSH/MSHA APPROVED RESPIRATOR FOR ACID GAS,DEPENDING ON THE
AIRBORN CONCENTRATION.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS
AFTER USE AND BEFORE EATING.
Supplemental Safety and Health
NONE

HCC:C1
Boiling Pt:B.P. Text:181F,83C
Vapor Pres:18.08
Vapor Density:0.62
Spec Gravity:1.01
pH:ACIDIC
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID.ODOR AND COLOR NOT REPORTED.
Corrosion Rate:CORROSIV

Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS,COMBUSTIBLE MATERIALS,ORGANIC
MATERIALS,METALS,ALKALIES,ACIDS.
Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION.
Hazardous Decomposition Products:NOT REPORTED.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.